A falling drop of rain water acquires the spherical shape due to

Viscosity
Surface Tension
Atmospheric pressure
Gravitational force
Surface Tension  Raindrops start out as round high in the atmosphere as water collects on dust and smoke particles in clouds. But as raindrops fall, they lose their rounded shape. A raindrop falling through the atmosphere forms as a roughly spherical structure due to the surface tension of water. This surface tension is the โ€œskinโ€ of a body of water that makes the molecules stick together. The cause is the weak hydrogen bonds that occur between water molecules. On smaller raindrops, the surface tension is stronger than in larger drops. The reason is the flow of air around the drop. Air flow on the bottom of the water drop is greater than the airflow at the top.

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